BINAP 1.1′-Binaphthyl-2.2′-diphemyl phosphine CAS 98327-87-8

Sinonim

BINAP
Binap
(?-Binap
1.1′-Binaphthyl-2.2′-Diphemyl Phosphine
2,2′-BIS(DIPHENYLPHOSPHINO)-1,1′-BINAPHTHYL
(?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Racemic-2,2′-bis(diphenylphosphino)-1,1′-binaphthy
racemic-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
S(-)-(1,1′-Binaphthalene-2,2′-Diyl)Bis(Diphenylphosphine)
RACEMIC-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHYL BINAP
2,2′-Bis-(diphenylphosphino)-1,1′-binaphthyl (Racemic BINAP)

CAS

98327-87-8

EINECS

619-338-0

InChIKey

MUALRAIOVNYAIW-UHFFFAOYSA-N

Massa Molar

622.69

Titik Melting

283-286°C(lit.)

Titik Boling

724.3±55.0 °C(Predicted)

Kelarutan air

Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Solubilitas

Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),

Penampilan

White to beige powder

warna

White to light beige

Merck

14,1223

BRN

5321443

Kondisi penyimpanan

Simpan di tempat gelap, atmosfer inert, suhu kamar

Sensitif

Sensitif Udara

MDL

MFCD00010805

Sifat fisik dan kimia

Melting point 280-285°C.

Penggunaan

Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.

Kode Risiko

36/37/38 – Irritating to eyes, respiratory system and skin.

Deskripsi Keselamatan

S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37/39 – Wear suitable gloves and eye/face protection
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

WGK Jerman

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