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S-TMQ CAS 26780-96-1

26780-96-1 – Names and IdentifiersNamepoly(1,2-dihydro-2,2,4-trimethyl-quinoline)SynonymsTMQral

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26780-96-1 – Names and Identifiers

Namapoly(1,2-dihydro-2,2,4-trimethyl-quinoline)
SinonimTMQ
ralox tmq
antioxidan
akos 90239
agerite ma
antigenerdf
VANLUBE(R) RD
antioxidanths
vanlube(r) rd
antioxidant rd
antioxidanthsl
agerite resin d
flectol(r) powder
acetonanil polymer
iflab-bb f1974-0002
flectol(r) pastilles
Rubber Antioxidant RD
Rubber Antioxidant TMQ
trimethyldihydroquinoline pol ymer
TRIMETHYLDIHYDROQUINOLINE POL YMER
POLY(1,2-DIHYDRO-2,2,4-TRIMETHYLQUINOLINE)
poly(1,2-dihydro-2,2,4-trimethylquinoline)
2,2,4-trimethyl-1,2,3,7-tetrahydroquinoline
poly(1,2-dihydro-2,2,4-trimethyl-quinoline)
2,2,4-trimethyl-1,2-dihydroquinoline polymer
1,2-dihydro-2,2,4-trimethylquinoline polymer
2,2,4-trimethyl-1,2-dihydroquinollne,polymer
2,2,4-trimethyl-1,2-dihydroquinoline, polymer
1,2-dihydro-2,2,4-trimethylquinoline oligomers
1,2-dihydro-2,2,4-trimethyl-quinolinhomopolymer
1,2-dihydro-2,2,4-trimethylquinoline homopolymer
POLYMERIZED 1,2-DIHYDRO-2,2,4-TRIMETHYLQUINOLINE
polymerized 1,2-dihydro-2,2,4-trimethylquinoline
2,2,4-trimethyl-1,2 dihydroquinoline(polymerized)
2,2,4-trimethyl-1,2 dihydroquinoline (polymerized)
CAS26780-96-1
EINECS500-051-3
InChIInChI=1/C12H17N/c1-9-8-12(2,3)13-11-7-5-4-6-10(9)11/h4,6-7,13H,5,8H2,1-3H3

26780-96-1 – Physico-chemical Properties

Rumus MolekulerC12H15N
Massa Molar173.25
Kepadatan1.08
Titik Melting72-94°C
Titik Boling>315°C
Titik Flash158.8°C
Kelarutan air<0.1 g/100 mL at 23 ºC
Solubilitas<0.1 g/100 mL at 23°C
Tekanan Vapor0Pa pada 25
PenampilanKuning
Kondisi penyimpanan2-8°C(protect from light)
Indeks Refraksi1.4870 (estimate)
Sifat fisik dan kimiaDensity 1.08
melting point 72-94°C
boiling point> 315°C
water solubility <0.1g/100 mL at 23°C
PenggunaanMainly used as rubber antioxidant, suitable for natural rubber and nitrile, styrene, Ethylene Propylene and chloroprene and other synthetic rubber

26780-96-1 – Risk and Safety

WGK Jerman2
RTECSTQ2625000

26780-96-1 – Upstream Downstream Industry

Material RawAniline
Acetone
Toluene
Sodium hydroxide
Hydrochloric acid

26780-96-1 – Reference Information

LogP3.9 at 25℃
gambaran keseluruhan2,2, 4-trimethyl-1, 2-dihydroquinoline polymer, alias antioxidant RD in Chinese, with CAS number 26780-96-1, is an industrial catalyst plastic rubber additive. 2,2,4-trimethyl -1,2-dihydroquinoline polymer chemical formula C36H45N3, molecular weight 519.76300, melting point 2-94°C, density 1.08, boiling point> 315°C, flash point 118.6°C, refractive index 1.548, vapor pressure 0.000262mmHg at 25°C. Synthetic rubber suitable for NR and CR, such as IR,BR and SBR, has excellent thermal and oxygen aging resistance, but cannot prevent bending and cracking of the rubber.
aplikasi2,2, 4-trimethyl-1, 2-dihydroquinoline polymer is an industrial catalyst or plastic rubber additive.
2,2, 4-trimethyl-1, 2-dihydroquinoline polymer is an industrial catalyst or plastic rubber additive. Examples of its application are as follows:
Prepare a material with sound insulation function. The sound insulation material includes 100 parts of nitrile rubber, zinc oxide, stearic acid, magnesium oxide, 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer, graphite powder, carboxyl silicone oil, accelerator, vulcanizing agent, wherein the material includes components in parts by weight: 100 parts of nitrile rubber, 4-7 parts of zinc oxide, 0.5-1.5 parts of stearic acid, 8-12 parts of magnesium oxide, 2,2, 4-trimethyl-1, 1.5-3.5 parts of 2-dihydroquinoline polymer, 7-12 parts of graphite powder, 3-6 parts of carboxyl silicone oil, 0.5-1.5 parts of accelerator and 2-6 parts of vulcanizing agent. The unit volume of the material is lighter than other sound insulation materials, which can reduce the weight in use, reduce the overall quality of the applied components, have good sound insulation and attraction performance, and have long-term stable and reliable sound insulation attraction performance.
persiapananiline and benzenesulfonic acid are put into a kettle reactor equipped with a condenser device in 8.9 parts by mass and 0.52 parts by mass respectively, heated and melted under stirring and raised to 155 ℃, acetone is added dropwise, and the temperature is kept at 155~165 ℃. after 13 parts by mass of acetone are added, the condensation reaction was carried out under the reflux of acetone at a temperature of 155~165 ℃ until the end point. The product is sent to a distillation tower, the water is distilled and acetone is recovered, then the reduced pressure distillation is carried out, and the fraction with boiling range of 130~140 ℃(2kPa) is collected to obtain monomer 2,2, 4-trimethyl-1, 2-dihydroquinoline. In the enamel reaction kettle, 8 parts of 30% hydrochloric acid are first added, water is added under stirring, diluted to about 17%, heated to 80 ℃, monomer is slowly added dropwise, and polymerization is carried out at a temperature of 95~98 ℃. After dropping the monomer, the reaction continued for 4 hours. 15% NaOH solution was added for neutralization to make the reaction material neutral. Then it is cooled, crystallized, filtered, washed and dried to obtain the finished product of 2,2, 4-trimethyl-1, 2-dihydroquinoline polymer.
menggunakanmainly used as rubber antioxidant, suitable for natural rubber and synthetic rubber such as nitrile, styrene butadiene, ethylene propylene and chloroprene

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